产品名称

英文名称：(R,R)-DACH-naphthyl Trost ligand

同义词

174810-09-4、(R,R)-DACH-naphthyl Trost ligand、N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)、(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)、1-Naphthalenecarboxamide, N,N'-(1R,2R)-1,2-cyclohexanediy、(1R,2R)-(+)-1,2-二氨基环己烷-N,N'-双(2-苯基膦-1-萘酰基)

产品性质

CAS编号：174810-09-4

分子式：C52H44N2O2P2

分子量：790.87

MDL号：MFCD02684551

PubChem编号：2734210

别名：(1R,2R)-(+)-1,2-二氨基环己烷-N,N'-双(2-苯基膦-1-萘酰基)

英文别名：174810-09-4|(R,R)-DACH-naphthyl Trost ligand|N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)|(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)|1-Naphthalenecarboxamide, N,N'-(1R,2R)-1,2-cyclohexanediy

规格或纯度：95%

英文名称：(R,R)-DACH-naphthyl Trost ligand

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：不对称烯丙基烷化反应的配体Asymmetric allylic alkylation ligand

IUPAC Name：2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

INCHI：InChI=1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m1/s1

InChi Key：VXFKMKXTPXVEMU-AWSIMMLFSA-N

Canonical SMILES：C1CCC(C(C1)NC(=O)C2=C(C=CC3=CC=CC=C32)P(C4=CC=CC=C4)C5=CC=CC=C5)NC(=O)C6=C(C=CC7=CC=CC=C76)P(C8=CC=CC=C8)C9=CC=CC=C9

Isomeric SMILES：C1CC[C@H]([C@@H](C1)NC(=O)C2=C(C=CC3=CC=CC=C32)P(C4=CC=CC=C4)C5=CC=CC=C5)NC(=O)C6=C(C=CC7=CC=CC=C76)P(C8=CC=CC=C8)C9=CC=CC=C9

WGK Germany：3

PubChem CID：2734210

敏感性：对湿度敏感

熔点：224-231°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritation

预防措施声明：P305+P351+P338,P280,P302+P352,P321,P264,P362+P364,P264+P265,P337+P317,P332+P317

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