产品名称

英文名称：Dichloro[1,3-bis(2,6-diisopropylphenyl)imidazolyl-2-idene](3-chloropyridyl)palladium

同义词

Pd(PEPPSI)IPr、(1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIDENE) (3-CHLOROPYRIDYL) PALLADIUM(II) DICHLORIDE、PEPPSI-SIPr catalyst、BLDKGTGQENJFON-UHFFFAOYSA-L、(1,3-Bis(2,6-diisopropylphenyl)imidazolidene) ( 3-chloropyridyl) palladium(II) dichloride、A859990、MFCD、[1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride, PEPPSI™-IPr 催化剂

产品性质

CAS编号：905459-27-0

分子式：C32H40Cl3N3Pd

分子量：679.46

MDL号：MFCD08457656

PubChem编号：16218181

别名：[1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride, PEPPSI™-IPr 催化剂

英文别名：Pd(PEPPSI)IPr|(1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOLIDENE) (3-CHLOROPYRIDYL) PALLADIUM(II) DICHLORIDE|PEPPSI-SIPr catalyst|BLDKGTGQENJFON-UHFFFAOYSA-L|(1,3-Bis(2,6-diisopropylphenyl)imidazolidene) ( 3-chloropyridyl) palladium(II) dichloride|A859990|MFCD

规格或纯度：≥98%

英文名称：Dichloro[1,3-bis(2,6-diisopropylphenyl)imidazolyl-2-idene](3-chloropyridyl)palladium

应用：· Kumada-Tamao-Corriu（KTC） 反应的催化剂（平衡1） · Negishi 偶联反应的催化剂（平衡2） · Suzuki 偶联反应的催化剂（平衡3） · Buchwald-Hartwig 胺化反应的催化剂（平衡4)

运输条件：常规运输

产品介绍：· Kumada-Tamao-Corriu（KTC） 反应的催化剂（平衡1） · Negishi 偶联反应的催化剂（平衡2） · Suzuki 偶联反应的催化剂（平衡3） · Buchwald-Hartwig 胺化反应的催化剂（平衡4)Product classM-P, Homogeneous Catalysts, M-N, N-Heterocyclic Carbene Ligands, M-C, IPr, PEPPSI Ligands, Pyridyl Ligands, Bidentate LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, CH-Activation, Kumada Coupling Reaction, Negishi Coupling Reaction, Oxidation, Sonogashira-Hagihara Coupling Reaction, Suzuki-Miyaura Coupling ReactionChemical propertiesChemical formulaC32H40N3Cl3PdEmpirical formula[(IPr)Pd(3-Cl-py)Cl2]Molecular weight679.47MetalPdTheoretical metal content16Physical statecrystallineColoryellowApplication• Catalyst for Kumada-Tamao-Corriu (KTC) reaction[1] (eq. 1)• Catalyst for Negishi coupling reaction[2] (eq. 2)• Catalyst for Suzuki coupling reaction[3] (eq. 3)• Catalyst for Buchwald-Hartwig amination reaction[4] (eq. 4)Applications & referencesPreparation of substituted heterobicyclic carboxylic acids, as well N-oxides and agriculturally accepted salts, which are applied in controlling plant growth.Reference WO2011045561Manufacture of pyrazol derivatives as modulators of cannabinoid receptors, which are useful in the treatment of obesity and overweight.Reference WO2008 074982Novel synthetic approach of glycine transport GT1 inhibitor sacrosine.Reference WO2007 060203Intramolecular direct arylation of aryl chlorides.Reference Synth. Comm. 2011, 41, 41 (DOI 10.1080/00397910903531755)Oxidation of secondary alcohols.Reference J. Org. Chem. 2011, 76, 1390 (DOI DOI 10.1021/jo102385u)Suzuki-Miyaura coupling reaction.Reference Org. Lett. 2011, 13, 146 (DOI 10.1021/ol1027283)Negishi coupling reactions.Reference Chem. Eur. J. 2006, 12, 4749 (DOI 10.1002/chem.20060020) ; Org. Lett. 1999, 1, 1323 (DOI 10.1021/ol9907872); J. Org. Chem. 2002, 67, 79 (DOI 10.1021/jo0105787)Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.Reference J. Org. Chem. 2011, 76, 1390 (DOI 10.1021/jo102385u)

IUPAC Name：1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazole;3-chloropyridine;dichloropalladium

INCHI：InChI=1S/C27H38N2.C5H4ClN.2ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;6-5-2-1-3-7-4-5;;;/h9-16,18-21H,17H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2

InChi Key：BLDKGTGQENJFON-UHFFFAOYSA-L

Canonical SMILES：CC(C)C1=C(C(=CC=C1)C(C)C)N2CN(C=C2)C3=C(C=CC=C3C(C)C)C(C)C.C1=CC(=CN=C1)Cl.Cl[Pd]Cl

Isomeric SMILES：CC(C)C1=C(C(=CC=C1)C(C)C)N2CN(C=C2)C3=C(C=CC=C3C(C)C)C(C)C.C1=CC(=CN=C1)Cl.Cl[Pd]Cl

WGK Germany：3

PubChem CID：16218181

熔点：230°C

象形图：

信号词：Warning

危险声明：H302 Harmful if swallowedH312 Harmful in contact with skinH332 Harmful if inhaled

预防措施声明：P261,P280,P302+P352,P321,P501,P264,P271,P270,P304+P340,P362+P364,P330,P301+P317,P317

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

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