产品名称

英文名称：Tetrabutylammonium iodide

同义词

Tetrabutylammonium iodide、311-28-4、Tetra-n-butylammonium iodide、TBAI、Tetrabutyl ammonium iodide、tetrabutylazanium iodide、tetrabutyl-ammonium iodide、Tetra-N-butylammoniumjodid、tetra butyl ammonium iodide、1-Butanaminium, N,N,N-tributyl-, iodide、tetrabutylam、TBAI、碘化四丁基铵

产品性质

CAS编号：311-28-4

分子式：C16H36NI

分子量：369.37

Beilstein号：3916152

EC号：206-220-5

MDL号：MFCD00011636

PubChem编号：67553

别名：TBAI|碘化四丁基铵

英文别名：Tetrabutylammonium iodide|311-28-4|Tetra-n-butylammonium iodide|TBAI|Tetrabutyl ammonium iodide|tetrabutylazanium iodide|tetrabutyl-ammonium iodide|Tetra-N-butylammoniumjodid|tetra butyl ammonium iodide|1-Butanaminium, N,N,N-tributyl-, iodide|tetrabutylam

规格或纯度：99%

英文名称：Tetrabutylammonium iodide

储存温度：充氩

运输条件：常规运输

产品介绍：易吸湿。溶于水和乙醇，微溶于氯仿。有刺激性。水中溶解度<5%。 离子对色谱试剂，相转移催化剂，极谱分析试剂。有机合成。 Tetrabutylammonium iodide (TBAI) has been used as a catalyst in the following reactions · Synthesis of O-benzyl-N-Boc-L-tyrosine benzyl ester from N-Boc-L-tyrosine. · Conversion of 8-fluoro-1-aminonaphthalene into 1-(8-fluoro-naphthalen-1-yl)piperazine hydrochloride. · Synthesis of 1-(2,4-dichlorophenyl)-5-(4-(4-iodobut-1-ynyl)phenyl)-4-methyl-N-(piperidin-1-yl)-1H-pyrazole-3-carboxamide from 4-(4-(1-(2,4-dichlorophenyl)-4-methyl-3-(piperidin-1-ylcarbamoyl)-1H-pyrazol-5-yl)phenyl)but-3-yn-1-yl methanesulfonate. Other reactions where TBAI can be used as a catalyst · TBAI-tert-butyl hydroperoxide system can catalyze the conversion of α-methyl styrene derivatives into allylic sulfones by reacting with sulfonylhydrazides under metal-free conditions. · Palladium(0)-catalyzed cross-coupling between benzylic zinc bromides and aryl or alkenyl triflates. · Three-component coupling of amines, carbon dioxide, and halides to form caTetrabutylammonium iodide (TBAI) has been used as a catalyst in the following reactions · Synthesis of O-benzyl-N-Boc-L-tyrosine benzyl ester from N-Boc-L-tyrosine. · Conversion of 8-fluoro-1-aminonaphthalene into 1-(8-fluoro-naphthalen-1-yl)piperazine hydrochloride. · Synthesis of 1-(2,4-dichlorophenyl)-5-(4-(4-iodobut-1-ynyl)phenyl)-4-methyl-N-(piperidin-1-yl)-1H-pyrazole-3-carboxamide from 4-(4-(1-(2,4-dichlorophenyl)-4-methyl-3-(piperidin-1-ylcarbamoyl)-1H-pyrazol-5-yl)phenyl)but-3-yn-1-yl methanesulfonate. Other reactions where TBAI can be used as a catalyst · TBAI-tert-butyl hydroperoxide system can catalyze the conversion of α-methyl styrene derivatives into allylic sulfones by reacting with sulfonylhydrazides under metal-free conditions. · Palladium(0)-catalyzed cross-coupling between benzylic zinc bromides and aryl or alkenyl triflates. · Three-component coupling of amines, carbon dioxide, and halides to form carbamates in the presence of cesium carbonate.

IUPAC Name：tetrabutylazanium;iodide

INCHI：InChI=1S/C16H36N.HI/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1

InChi Key：DPKBAXPHAYBPRL-UHFFFAOYSA-M

Canonical SMILES：CCCC[N+](CCCC)(CCCC)CCCC.[I-]

Isomeric SMILES：CCCC[N+](CCCC)(CCCC)CCCC.[I-]

WGK Germany：3

RTECS：BS5450000

PubChem CID：67553

Reaxy-Rn：3916152

溶解性：Soluble in water and methanol. Insoluble in benzene.

密度：1.2

敏感性：对湿度和光线敏感

熔点：145-148°C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302 Harmful if swallowedH318 Causes serious eye damage

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P305+P354+P338,P317,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US),Eyeshields,Gloves

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