产品名称

英文名称：Grubbs Catalyst

同义词

Umicore Grubbs Catalyst M102、GRUBBS 1 代催化剂

产品性质

CAS编号：172222-30-9

分子式：C43H72Cl2P2Ru

分子量：822.96

MDL号：MFCD01090946

别名：GRUBBS 1 代催化剂

英文别名：Umicore Grubbs Catalyst M102

规格或纯度：Ru 12.3%

英文名称：Grubbs Catalyst

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：Ruthenium-Based Metathesis Catalysts,widely used in organic synthesis.Ruthenium-Based Metathesis Catalysts,widely used in organic synthesis.Product classM-P, Homogeneous Catalysts, M-C, Grubbs Catalyst® 1st Generation, Carbene Ligands, Phosphorus Ligands - AchiralReaction typeAlkene Metathesis, Acyclic Diene Metathesis, Cross Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self MetathesisChemical propertiesChemical formulaC43H72Cl2P2RuEmpirical formulaRu(PCy3)2(benzylidene)Cl2Molecular weight822.96MetalRuTheoretical metal content12Physical statepowderColorpurpleApplications & referencesFormal Synthesis of (-)-Haliclonin A Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.Reference Org. Lett. 2020, 22, 13, 5046–5050Formylation of a metathesis-derived ansa[4]-ferrocene a simple route to anticancer organometallics.Reference Dalton Trans. 2020, (doi.org/10.1039/D0DT01975E)Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.Reference RSC Adv. 2020,10, 24840-24846Asymmetric total synthesis of the naturally occurring antibiotic AnthracimycinReference Org. Lett. 2020, 22, 14, 5550–5554Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.Reference Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)

Canonical SMILES：C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru

WGK Germany：3

UN Number：1325

密度：1.433

敏感性：对空气、光线敏感

熔点：153°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH228 Flammable solid

预防措施声明：P261,P305+P351+P338,P210

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

产品包装