产品名称

英文名称：(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl

同义词

100165-88-6、99646-28-3、(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl、153305-67-0、2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl、(R)-Tol-BINAP、(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl、(S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL、R-

产品性质

CAS编号：100165-88-6

分子式：C48H40P2

分子量：678.78

MDL号：MFCD01311709

PubChem编号：4189906

英文别名：100165-88-6|99646-28-3|(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl|153305-67-0|2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl|(R)-Tol-BINAP|(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl|(S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL|R-

规格或纯度：98%

英文名称：(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl

储存温度：充氩

运输条件：常规运输

产品介绍：(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO3, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides.It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO3, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides.It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.

IUPAC Name：[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane

INCHI：InChI=1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3

InChi Key：IOPQYDKQISFMJI-UHFFFAOYSA-N

Canonical SMILES：CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C

Isomeric SMILES：CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C

WGK Germany：3

PubChem CID：4189906

Reaxy-Rn：5786041

溶解性：Insoluble in water.

敏感性：对湿度和空气敏感

熔点：252-256°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：Eyeshields， Gloves， type N95 (US)， type P1 (EN143) respirator filter

产品包装