产品名称

英文名称：Methyl Isocyanoacetate

同义词

Methyl isocyanoacetate、39687-95-1、Methyl 2-isocyanoacetate、Isocyanoacetic acid methyl ester、Isocyano-acetic acid methyl ester、MFCD00000006、methylisocyanoacetate、methyl-isocyanoacetate、methyl isocyano-acetate、methyl alpha-isocyanoacetate、GEO-03019、AKOS0159

产品性质

CAS编号：39687-95-1

分子式：C4H5NO2

分子量：99.09

Beilstein号：3537960

MDL号：MFCD00000006

PubChem编号：547815

英文别名：Methyl isocyanoacetate|39687-95-1|Methyl 2-isocyanoacetate|Isocyanoacetic acid methyl ester|Isocyano-acetic acid methyl ester|MFCD00000006|methylisocyanoacetate|methyl-isocyanoacetate|methyl isocyano-acetate|methyl alpha-isocyanoacetate|GEO-03019|AKOS0159

规格或纯度：>97.0%(GC)

英文名称：Methyl Isocyanoacetate

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：异氰乙酸甲酯在固相儿茶酚-铜网络催化剂存在下与羰基化合物发生直接羟醛缩合反应生成相应的恶唑啉。它还参与四组分 Ugi 缩合反应产品应用异氰乙酸甲酯已被用于铜催化的、非对映选择性合成恶唑啉类Product ApplicationMethyl isocyanoacetate has been used in the diastereoselective synthesis of oxazolines catalyzed by copper；Methyl isocyanoacetate is used in the copper-catalyzed, diastereoselective synthesis of oxazolines. It is involved in the direct aldol reaction with carbonyl compounds to prepare corresponding oxazoline by using catechol-copper network catalyst. Further, it is also involved in four-component Ugi condensation reaction. It undergoes asymmetric aldol reaction with fluorinated benzaldehyde using gold(I) as a catalyst.

IUPAC Name：methyl 2-isocyanoacetate

INCHI：InChI=1S/C4H5NO2/c1-5-3-4(6)7-2/h3H2,2H3

InChi Key：CRXFROMHHBMNAB-UHFFFAOYSA-N

Canonical SMILES：COC(=O)C[N+]#[C-]

Isomeric SMILES：COC(=O)C[N+]#[C-]

WGK Germany：3

PubChem CID：547815

Reaxy-Rn：3537963

溶解性：Miscible with organic solvents. Slightly miscible with water.

密度：1.09

敏感性：对光、热、湿度敏感

折光率：1.42

闪点(℉)：183.2 °F

闪点(℃)：84°C(lit.)

沸点：75°C/10mmHg(lit.)

象形图：

信号词：Danger

危险声明：H331 Toxic if inhaledH314 Causes severe skin burns and eye damageH302 Harmful if swallowedH312 Harmful in contact with skinH332 Harmful if inhaled

预防措施声明：P261,P280,P302+P352,P321,P405,P501,P264,P260,P271,P270,P301+P330+P331,P304+P340,P363,P403+P233,P362+P364,P330,P301+P317,P305+P354+P338,P317,P302+P361+P354,P316

个人防护装备：Faceshields， full-face respirator (US)， Gloves， Goggles， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

产品包装